The effect of inhibitors on the electrochemical deposition of. Chemical mechanical polishing cmp is one of the most essential processes in semiconductor manufacturing. Our ultrasonic technology creates a directionally concentrated and repeatable flow signal despite bubbles and temperature fluctuations. Its role is to passivate the surface so that the oxidation rate can be controlled, as well as to. Design, filter, analyze and summarize data using statistical software. White et al, materials research society symposium proceedings 2007, 991advances and challenges in chemical mechanical planarization, 145 150. Particles are reduced through changes in brush and process conditions. Transformation of silica fume into chemical mechanical. Preparation and characterization of slurry for chemical.
Cmp slurries sold and distributed by rohm and haas electronic materials cmp, inc. Characterization of cmp slurries dispersion technology. New test method for determining density of cmp slurries semi. Standard deviation of the mean particle size characterization is 2 nm for 10% slurry and 0. As a pioneer in chemical mechanical planarization cmp slurries, cabot microelectronics commercialized our original semisperse products in the 1980s for 250nm cmp applications. Flow controller for cmp slurry control products inc. Duponts pcmp offerings are part of our ekc technology portfolio. Flowmaster cmp slurry delivery system versum materials. Pdf characterization of cmp slurries using densitometry and. The basic chemical factors of metal cmp slurry are oxidizers, chelating. Slurry components in metal chemical mechanical planarization cmp process. It can be thought of as a hybrid of chemical etching and free. Interview with adam manzonie, global slurry business director for cmp technologies. The companys vision is to become the world leader in shaping, enabling and enhancing the performance of surfaces, so the company is leveraging its expertise in cmp slurry formulation, materials and.
This productionproven, selective tungsten slurry is a highpurity slurry based on fumed silica and hydrogen peroxide technology. Chemical mechanical polishing cmp is used in microelectronics industry to planarize and pattern metal and dielectric layers. Overcome challenges in tsv cmp via slurry formulation. Decrease in the sizes of the devices and introduction of new materials necessitate improved control of the cmp that can be achieved by studying the slurry chemical and particulate properties. Hitachi chemical metal cmp slurry and lowk material. Iiiv cmp background iiiv cmp slurry formulation development at basf basic concept development additive, component screening test on iiiv patterned wafers conclusion 15. Redundant systems and a broad range of analy cal capabili es help deliver the most uniform and accurate blend. Our facility is designed as integrated manufacturing from raw materials to final products which are synthesis abrasives and polishing slurry products. Us5954997a chemical mechanical polishing slurry useful. Finetune slurry chemistry to get desired polishing rates and metrology performance for feol slurries. Request pdf overcome challenges in tsv cmp via slurry formulation along with the advancement of ic 3d technology, tsv through silicon via has been paid close attention to practically enable. The emphasis is on chemical mechanical polishing cmp.
Fujifilm electronic materials barrier cmp slurries are designed to remove the barrier metals that are exposed following the copper clearing step as well as to planarize all films across the wafer surface. Chemical mechanical polishing cmp ara philipossian intel corporation 1999 arizona board of regents for the university of arizona outline of the tutorial section a. Post cmp cleaning chemicalssc1,nh4oh, and hf have been used since cmp process was introduced. Beol cmp is used to form metal interconnects including al, w, and cu. It is surprisingly found that this process causes the drift of ph over time to be very significantly reduced. A 3d printed polishing pad for chemicalmechanical planarization cmp comprises a microlattice including a plurality of layers of extruded filaments arranged in a crisscross pattern. Vaisala offers inline, realtime, reliable, precise and costeffective metrology for wet chemistry concentration measurements which can replace expensive and complex analyzers used in fab chemical process monitoring and fault detection as well as cmp slurry composition and concentration control. The effects of the inhibitor on cu cmp performance, including blanket removal rate, dishing and cu surface roughness were evaluated. Tungsten slurry semisperse w200 cabot microelectronics. Fujifilm electronic materials front end cmp slurries are designed for devices that utilize advanced transistor technologies such as highk metal gates, advanced dielectrics, 3dimensional finfet. The fundamental mechanism of cmp is to create soften surface layer by chemical reaction and then, mechanical force by abrasive particles remove soften layer.
Since then the number of materials being polished in various cmos process flows has steadily grown, as shown in figure 1. Cmp process has been developed through equipment, functional slurries and pad, disk. To transform the silica byproduct into cmp slurry, characterization of the silica byproduct, chemical dissolution of silica and controlled precipitation in the nanosize, slurry formulation, cmp testing and. Our newest technical video and infographic features best practices and techniques for minimizing slurry foaming via proper mixing and handling. To get involved, join the semi international standards program at. Moreover, adetailed electrochemical investigation of cuand ru behavior in the reported chemical system is lacking. Many advanced chemical mechanical planarization cmp slurries contain organic components that can cause foaming if not handled correctly. Aqueous formulations employed for postcmp pcmp cleaning are designed to protect the planarized metals and dielectrics preventing metal corrosion while providing a smooth defect free wafer surface. Cmp treatment cmpbg wastewater treatment chemical mechanical polishing cmp is an essential process in the semiconductor fabrication. Cmp slurries for increasingly complex process requirements.
Pdf slurry components in metal chemical mechanical. Foaming cmp slurry mixing and handling considerations. Analysis of ceo chemical mechanical planarization slurries. Contentsshow how generated in some industries slurry is man made for disposal as a waste product of a particular dusty material for. Abrasivefree and ultralow abrasive chemical mechanical. In order to achieve this balance, a corrosion inhibitor is introduced into the formulation. Cerium dioxide ceo2 particles are commonly used in cmp slurries. The effects of the inhibitor on cu cmp performance, including blanket removal rate, dishing and cu surface. Slurry is automatically generated in the process in industries for further processing to obtain the intermediate or end product. Decrease in the sizes of the devices and introduction of new materials.
Wo1998042791a1 chemicalmechanical polishing slurry. Product safety assessment chemicalmechanical planarization. The chemical mechanical planarization cmp protocols needed to process such structures are associated with several challenges, one of which is to designscreen slurry formulations required to. Using a chemical slurry formulation and mechanical polishing process to remove unwanted conductive or dielectric materials, cmp enables chipmakers to achieve higherperformance chips for advanced. Cabot microelectronics corporation qed technologies. W cmp slurry 1532 ppm fe feox very difficult to remove 1 d. Chemical mechanical planarization of ruthenium using. Cmp solutions versum materials enhanced portfolio of offerings to the chemical mechanical planarization cmp market provides an integrated solution to our customers in the ic segment. Fujifilm planar solutions barrier cmp slurries are designed to remove the barrier metals that are exposed following the copper clearing step as well as a portion of the intermetal dielectric. Dec 19, 2008 epoch is a taiwanbased company specializing in the development, manufacture and sale of copper cmp slurries and cmp cleaning solutions to the semiconductor industry, as well as color filter. A slurry is a sloppy mixture, which is generated in different varieties.
Redundant systems and a broad range of analytical capabilities help deliver the most uniform and accurate blend. Lynn fuller, professor cmp page 2 rochester institute of technology microelectronic engineering cmp chemical mechanical planarization. One of the commercial slurry products developed as a result of these requests is dows optiplane 2118 slurry, a lowabrasive, acidic ph silica slurry used for planarizing dielectric films in advanced cmp. It uses a slurry containing both nanoparticles and functional chemicals. Fight fires in accordance with the material that is burning. Published jan 1, 2014 application note cmp filter characterization with leading slurry particles download pdf 587. Addressing cmp slurry market drivers with the optiplane. A systematic approach to slurry formulation for oxide cmp at. Cmp requires the balance of removal rates, planarization and surface quality. Applications engineer feol in mesa, arizona careers. Cmp or bg wastewater quality control discharge cmp and backgrind wastewater treatment cmp treatment cmp bg wastewater treatment chemical mechanical polishing cmp is an essential process in the semiconductor fabrication. Cmp slurry distribution systems for your benefit youtube. Us patent 8551202 from cabot microelectronics describes ultralow abrasivecontaining slurry formulation 0. Cmp is a surface polishing and material removal process involving both chemical attack and abrasive removal.
Marketleading products are available to meet a broad range process and technology requirements. This report discusses the technology trends, products, applications, and suppliers of materials and equipment. A slurry formulation utilizing a ferric salt tungsten oxidizer, an ammonium persulfate titanium oxidizer, a fatty acid suspension agent, alumina particles with a. With continuous improvement of some of these slurries, enhanced versions are still in use and key to our customer solutions today. Challenges for w postcmp cleaners linx consulting llc. Post cleaning chemical of tungsten chemical mechanical. Its importance becomes highly underscored at the advanced device toward sub 14 nm scaling. Method for determining density of chemical mechanical polish cmp slurries.
Chemical mechanical planarization cmp slurries selection. A major aspect of maintaining cmp slurry health is keeping the concentration of the oxidizer often h2o2 constant as per specification in the slurryoxidizer blend. Contentsshow how generated in some industries slurry is man made for disposal as a waste product of a particular dusty material for transportation to another location by pumping. Specific slurry formulations are different depending on the materials to be polished. The incorporation of lowdielectricconstant lowk spinonglass sog into multilevel interconnection schemes necessitates the evaluation of cmp compatibility of this new group of materials. Slurry formulations were created through the combination of commercially available chemical reagents and abrasive particles, as previously reported 12. The effect of inhibitors on the electrochemical deposition. Based on our knowledge of slurry formulation design, we continuously produce leading and advanced final polishing slurry for silicon wafer substrate. Capturing large particles from slurry with high sol. Slurry d most provides the best protection to the cu surface. Panarization cmp slurry optimization for advanced nodes.
Standard deviation of the acoustic attenuation characterization of the median and mean particle size of the concentrated intact cmp slurry is in the range nanometers. Characterization of cmp slurries using densitometry and. In general, cmp slurries are composed of abrasive, oxidizer, organic compounds such as dispersant and passivation agent, and deionized water diw. A ceriabased singlecomponent slurry with various aspects of the slurry formulation being optimized to specific customer requirements for the material stack, feature sizes and densities, and wafer type. Front end cmp slurries cmp semiconductor materials. Semisperse w2000 series is the industry benchmark for tungsten cmp. Chemical mechanical planarization cmp slurries contain a small amount of large particles that will contribute to microscratches on a wafers surface. Wo2015120430a1 3dprinted polishing pad for chemical. Dupont offers a broad cmp slurries portfolio that includes a wide range of. Chemicalmechanical polishing cmp, is a technique used in semiconductor fabrication for planarizing a wafer or other. Ruthenium cmp integration for dualdamascene copper. Abrasive for chemical mechanical polishing intechopen. Mix design methods for slurry seal microsurfacing and for. A chemical mechanical polishing slurry comprising a film forming agent, an oxidizer, a complexing agent and an abrasive, and a method for using the chemical mechanical polishing slurry to remove copper.
Cmp filter characterization with leading slurry particles. Characterization of sio2 slurry samples used in chemical mechanical polishing using size measurement by dls and zeta potential measurement large particles and aggregates are detrimental to the. Scratch reduction has been mainly made through pad, slurry changes. White knights highpurity pumps feature pneumatic logic, which reduces pulsation to prevent shear while gently pumping slurry. We recently met up with adam manzonie, global slurry business director, cmp technologies, dow electronic solutions, to discuss the market drivers that led to the introduction of the business new optiplane cmp slurry platform. Cabot microelectronics corporation announces agreement to. Optimal w removal balances chemical oxidation of hard metallic w into softer oxidized surface layers and subsequent removal of the oxidized layers by mechanical motions of abrasive particles. In the lab, blending of the materials that are to be used in the field is done in varying proportions to select the proper formulation. Chemical mechanical planarization of ruthenium using sodium.